Nano-sponges of solid acid transform carbon dioxide to fuel

Aug 02 2020

Researchers at the Tata Institute of Fundamental Research have developed nano solid acids that transform CO2 directly to fuel (dimethyl ether) and plastic waste to chemicals (hydrocarbons).

Solid acids are among the most essential heterogeneous catalysts, which have the potential to replace environmentally harmful liquid acids in some of the most important processes, such as hydrocarbon cracking, alkylation, as well as plastic waste degradation and carbon dioxide to fuel conversion.

Two of the best-known solid acids are crystalline zeolites and amorphous aluminosilicates. Although zeolites are strongly acidic, they are limited by their inherent microporosity, causing extreme diffusion limitation; and although aluminosilicates are mesoporous, they suffer from low acidity and moderate stability. Thus, it is a synthetic challenge to design and synthesize solid acids with both strong acidities like zeolites and textural properties like aluminosilicates, speculated as "amorphous zeolites," which are ideally strongly acidic amorphous aluminosilicates.

By using the techniques of bicontinuous microemulsion droplets as a soft template, Prof. Vivek Polshettiwar's group at Tata Institute of Fundamental Research (TIFR), Mumbai, synthesized amorphous zeolites with a nano-sponge morphology, exhibiting both zeolitic (strong acidity) and amorphous aluminosilicate (mesoporous high surface area) properties.

The presence of -like bridging silanol in AAS was proved by various catalytic reactions (styrene oxide ring-opening, vesidryl synthesis, Friedel-Crafts alkylation, jasminaldehyde synthesis, m-xylene isomerization, and cumene cracking), which requires strong acidic sites and larger pore sizes. The synergy between strong acidity and accessibility was reflected in the fact that AAS showed better performance than state-of-the-art zeolites and amorphous aluminosilicates. This was also confirmed by detailed solid-state NMR studies.

Thus, it was clear that the material possesses strongly acidic zeolite-like bridging silanol sites, even though materials are not crystalline but amorphous. Therefore, they fall into a new class of materials at the interface between crystalline zeolite and amorphous aluminosilicate.

Thus, the approach may allow the development of solid  catalysis for plastic degradation as well as carbon dioxide to fuel at the significant rates, scales, and stabilities required to make the process economically competitive. The protocol has scientific and technological advantages, owing to its superior activity and stability.

The work is published in Nature Communications.

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Tata Institute of Fundamental Research

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